Germany 2006 Final: Zinedine Zidane was then sent off in the 110th minute of the game after headbutting Marco Materazzi in the chest, so he did not participate in the penalty shootout which Italy won 5–3 courtesy of David Trezeguet’s shot rattling the crossbar. Neither Fabien Barthez nor Gianluigi Buffon made a single save in the penalty shootout.